Petroleum Science >2012,??Issue 1:??82-88 DOI: https://doi.org/10.1007/s12182-012-0186-9
Effect of ultrasonic irradiation on rheologicalproperties of asphaltenic crude oils Open?Access
文章信息
Ultrasonic Research Group, Chemical and Petroleum Engineering Department, Sharif University of Technology, Azadi Ave., Tehran, Iran; Chemical and Petroleum Engineering Department, Sharif University of Technology, Azadi Ave., Tehran, Iran;Chemical and Petroleum Engineering Department, Sharif University of Technology, Azadi Ave., Tehran, Iran;Ultrasonic Research Group, Chemical and Petroleum Engineering Department, Sharif University of Technology, Azadi Ave., Tehran, Iran;Chemical and Petroleum Engineering Department, Sharif University of Technology, Azadi Ave., Tehran, Iran;Ultrasonic Research Group, Chemical and Petroleum Engineering Department, Sharif University of Technology, Azadi Ave., Tehran, Iran
文章摘要
for different time intervals in addition to the effect of temperature on viscosity behavior of heavy crude oils
were investigated using a series of steady shear flow and oscillatory tests. The colloidal structural evolutions
of flocs in oil samples were illustrated by analysis of the size distribution of flocculated asphaltene particles
(confocal microscopy tests). The rheological investigations indicate that the ultrasonic irradiation dissolved
heavy components in crude oil. After ultrasonic treatment, the Kouh-e-Mond crude oil was found to be
pseudoplastic. In addition, confocal microscopy confirms that there was an optimum duration for ultrasonic
irradiation, at which the viscosity and flocculation rate of asphaltenic crude oils reduced to the minimum
values. The optimum was found to be approximately 40 min for the Kouh-e-Mond crude oil. Experimental
results illustrate that the ultrasonic irradiation could disaggregate heavy colloid components in crude oil,
and breakdown of asphaltene molecules would only occur in a specific time interval of irradiation. Also
according to the temperature sweep test, the oil temperature rise caused by ultrasonic irradiation was not the
main reason for rheological changes of the crude oil and this alteration may be due to physical and chemical
phenomena induced by sonication in crude oil.
关键词
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Asphaltene, ultrasonic technology, pseudoplastic property, viscoelastic property, yield stress,flocculation time